1. Spike (Buffy the Vampire Slayer and Angel) - I suppose he turned into a semi-good guy by the end there...
2. Cigarette Smoking Man (the X-files) - was always really intrigued by him
3. Krycek (the X-files) - mostly because he was totally hot, haha
4. Lex Luthor (Smallville) - well, he's not fully a villain yet, but his hint of evil has always been there
5. Julie Cooper (the OC) - "this town's really only big enough for one manipulative bitch"
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